• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A multi-layer non-reflecting film uniform in refractive index and having favorable optical characteristics which comprises at least one layer made of a mixture of Ta2O5 and ZrO2 containing 5 to 25% of Ta2O5.
    公开号:SU1258323A3
    申请号:SU2788558
    申请日:1979-07-10
    公开日:1986-09-15
    发明作者:Козава Токудзиро
    申请人:Олимпус Оптикал Ко.,Лтд (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to a multilayer absorbing coating, in particular to a multilayer absorbing coating with optical quality parameters and a higher coating strength.
    The purpose of the invention is to increase the durability of the coating and the optical characteristics,
    The table shows the specific compositions of the inner layer, including ZrO and.
    Components
    The number of components, wt.%, In samples
    ZrO,
    95
    73
    90
    Scho,
    25
    ten
    FIG. 1 shows the proposed two-layer absorbing coating, incision; Fig. 2 shows the proposed three-layer absorbing coating, cut; Fig. 3 shows the curves characterizing the optical characteristics of the proposed two-layer absorbing coating; in fig. 4 - the same, the known two-layer absorbing coating; Fig. 5 shows the curves characterizing the optical characteristics obtained by calculating for a two-layer absorbing coating; Fig. 6 shows the curves characterizing the optical characteristics of the proposed three-layer absorbing coating; Fig. 7 is the same as the well-known Three Layer Absorbent Coating; Fig. 8 shows the curves characterizing the optical characteristics obtained by calculation for a three-layer absorbing coating.
    This invention relates to a multilayer
    This is an absorbing coating, in which a mixture consisting of + is used instead of ZrO in at least one of several layers, and has a refractive index of 2.13, and ZrOz - 1.96 - 1.98. The layer consisting of + 2r must; have a ratio of 1:19 1: 3, i.e., 5-25 wt.%.
    FIG. 1, the symbol G denotes a glass substrate made of SFS-5 glass, on which there is a coating of which thickness is ET (2 and which is applied by evaporation in a vacuum (layer R,), as well as a film of MgF, the thickness of which is I / 4, obtained by evaporation in a vacuum (second layer Rj). The optical characteristics of the proposed absorbing film of the composition described are shown in Fig. 3, where the curves ci, b and c represent the optical characteristics of the absorbing coatings manufactured at substrate temperatures 260, 300 and 330 ° C respectively Fig. 4 shows the optical characteristics of a conventional two-layer absorbing coating of the same composition as on fit t, the substrate G being made of SFS-5 glass, the ZrO film is L / 2 thick, forming the layer R (and the MgF film has a thickness J74, forming the second layer Rg. In Fig. 4, the curves a, b and c correspond to optics, the typical characteristics of multilayer absorbing coatings made at substrate temperatures of 260, 300 and 330 C, respectively.
    As can be seen from the data presented in FIG. 3 and 4, the proposed absorptive coatings made of layers of TajOg + ZrOg have better optical characteristics than the known ones consisting of layers of j ZrO. Fig. 5 shows the calculated values for the absorbent coating of the same composition as the proposed proposed absorbing coating, as well as for the known coating. As seen in FIG. 5, the optical characteristics of the proposed bilayer absorbing coatings are very close to the calculated values. The MgF layer has high strength in the proposed bilayer absorbing coating. Since it is manufactured at a substrate temperature above 2SO C,
    The proposed three-layer absorbing coating consists of white glass (h 1, 5230), which is used as a substrate G, a CeF film (of which thickness is 4), which is the first layer R, of a film of TajO + ZrOj (having a thickness of L / 2), which is the second layer of RJ, as well as the MgFg plies (with a thickness of il / 4), which is the third layer. Fig. 6 shows the optical characteristics of this absorbent coating. The curves Q, b, c, and i represent the optical characteristics of multilayer absorbing coatings, which are made at substrate temperatures 1AO, 220, 260, and respectively. FIG. 7 shows the optical characteristics of the known three-layer absorbing coatings, which use white glass as the substrate G, a film made of CeF with thickness J / 4 as the first layer R, a film made from ZrO with thickness L / 2 as the second layer Rj, and a film from MgF, 9/4 thick as the third layer of RY Curves a, b, c. and d (Fig. 7) are the optical characteristics of multilayer Absorbing Coatings, which are made at substrate temperatures of 140, 200, 260 and 320 ° C, respectively. When comparing the results presented in FIG. 6 and 7, it is understood that the proposed three-layer absorbing coatings have better optical characteristics than the known ones. FIG. Figure 8 shows the calculated values of the optical characteristics for a three-layer absorbing coating of the same composition as the three-layer absorbing coatings described above. The optical characteristics of the proposed three-layer absorbing coating shown in FIG. 6 is very similar to the results shown in Fig. 8. The description given relates to a first embodiment which uses a TaOy-i-ZrO foam as the first layer that is in contact with the glass substrate, as well as to the second embodiment, in which there is a first layer of thickness A / 4, a second layer of thickness and a third layer of thickness X / A, the second layer consisting of, -t-ZrOj. However, this invention is not limited to these options. It is also applicable to multilayer absorptive coatings, with the best optical characteristics, in which TajOy + ZrOj is used in different layers. For example,
    multilayer absorbing coatings with the best optical properties can be obtained using a film of
    5 10 is 20 25 o ..., j
    five
    0
    Ta O + ZrOj as the first layer in a two-layer coating, which consists of a first layer of thickness / 4, as well as a second layer of thickness; / 4, or using a film of Ta Oy + ZrO as the second layer in a three-layer coating, which consists of a first layer 3 I / 4 thick, a hot layer thick, and a third layer I / 4 thick. In the cases related to the said three-layer coating, which contains the first layer with thickness L / 4, the second layer with acid, and also the third layer with thickness C / 4, or with the coating. Which contains the first layer with a thickness of 3/4, the second layer with a thickness. / 2, as well as a third layer with a thickness of / 4, you can get a first layer of thin films with a high refractive index interlaced with a film, having a low refractive index, which is equivalent to the first layer that has the necessary intermediate refractive index (layer has a thickness L /four) . In this case, a film of thickness X / l from Ta, jO, + Zr02 is used as the second layer. In addition, it is advantageous to produce a two-layer coating using a layer equivalent to the first layer R ,, which has a thickness L / 2. The layer is made by evaporating coating with a very thin film Rj of MgFj or A1.P, as well as a relatively thin film of Rj from Ta O + ZrOj in combination with a film of MgFj or a similar substance with a thickness of 4. In this case, it is possible to obtain a multilayer absorbing coating with optical characteristics that are very close to the calculated ones, since the spectral reflective characteristic of the multilayer absorbing coating can be corrected by ms. More successfully using a thin film R, made of MgF or a similar substance in an equivalent layer, forming another relatively thin layer of R., so that the refractive index is the same when applied.
    It is possible to manufacture multilayer absorbing coatings with high strength and best optical properties by using Ta Oj + ZrOj films in layers of various multilayer coatings. The invention allows the manufacture of multilayer
    absorbing coatings that are not affected by temperature by creating thin layers when they are applied by evaporating the mixture and ZrOj in vacuum. However, it is necessary to choose a high substrate temperature to obtain a durable film by coating with evaporation in vacuum of MgF (for example, Ta Oy films + can be successfully obtained even with such a high substrate temperature) -. Since Ta Oy + ZrO films have a high durability during sputtering by evaporating such a high temperature in vacuum, it is possible to impart greater strength to each layer in multilayer absorbent coatings. The test of the strength of the semi-curable coatings was performed by abrading the film surface by
    gum with sandpaper, which is moved over the surface of the film at a speed of 30 mm / s. The tested films were examined with a microscope. On
    All samples of the films obtained according to the invention were not found scratched with bright light. A small amount of small or medium scratches was found under dark lighting. On samples obtained by known technology, it was found, respectively, a large and countless number of scratches,
    The proposed multilayer layering has high strength and optical characteristics that are very close to theoretically calculated values.
    Phage. 2
    .
    sh
    500
    f - jff / fifffa & olmy (fr)
    twS
    "Y. Dunsha (fr)
    OSSh O
    t
    ig.5
    Dtna 8vmy (Fri)
    games €
    Mffutn Waves (Fri)
    D / SHNI (fffn) Rig.7
    Fy
    D (Shina Vvyna {t1
    Editor M.Petrova
    Compiled by G. Burovtseva
    Tehred M. Khodanich Proofreader 0. Lugov
    Order 5043/60 Circulation 457 Subscription
    VNIIPI USSR State Committee
    for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5
    Production and printing company, Uzhgorod, Projecto st., 4
    权利要求:
    Claims (1)
    [1]
    MULTI-LAYER ABSORBING COATING, comprising at least two layers - an inner one based on Zr0 2 and an outer one made of MgF z. Characterized in that, in order to increase the coating strength and optical characteristics, the inner layer additionally contains Ta 2 0y in the following ratio of components, wt. X:
    ZrOj 75-95
    Ta 2 0 5 5-25 §
    SB with
    Si
    00 no 00
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    同族专利:
    公开号 | 公开日
    DE2927856C2|1983-06-01|
    US4260222A|1981-04-07|
    JPS5522704A|1980-02-18|
    DE2927856A1|1980-01-24|
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    GB1149489A|1965-05-24|1969-04-23|Asahi Glass Co Ltd|Infra-red reflecting glass and method of making it|
    CH527916A|1970-04-13|1972-09-15|Balzers Patent Beteilig Ag|Process for producing a highly refractive, transparent oxide layer|
    US3761160A|1972-05-31|1973-09-25|Optical Coating Laboratory Inc|Wide band anti-reflection coating and article coated therewith|DE3009533C2|1980-03-12|1986-11-06|D. Swarovski & Co., Wattens, Tirol|Covering with medium refractive index, process for its production and use of the covering|
    DE3026703C2|1980-07-15|1983-01-27|Will Wetzlar Gmbh, 6330 Wetzlar|Process for the production of an anti-reflective coating on a transparent material such as an optical glass|
    JPS57130001A|1981-02-05|1982-08-12|Canon Inc|Low polalization achromatic beam splitter|
    US4399194A|1981-12-30|1983-08-16|Rca Corporation|Transparent conductive film|
    JPS635723B2|1983-02-23|1988-02-04|Canon Kk|
    US4594605A|1983-04-28|1986-06-10|Rca Corporation|Imaging device having enhanced quantum efficiency|
    US4689873A|1983-04-28|1987-09-01|Rca Corporation|Imaging device having two anti-reflection layers on a surface of silicon wafer|
    NL8301652A|1983-05-10|1984-12-03|Philips Nv|METHOD FOR APPLYING MAGNESIUM FLUORIDE LAYERS AND ANTI-REFLECTIVE LAYERS OBTAINED BY THIS METHOD|
    US4578527A|1983-11-16|1986-03-25|Optical Coating Laboratory, Inc.|Articles having improved reflectance suppression|
    US4596745A|1984-05-04|1986-06-24|Cotek Company|Non-glare coating|
    US4694218A|1984-05-04|1987-09-15|Cotek Company|Non-glaze coating for a cathode ray tube|
    US4755673A|1984-10-24|1988-07-05|Hughes Aircraft Company|Selective thermal radiators|
    US5181141A|1989-03-31|1993-01-19|Hoya Corporation|Anti-reflection optical element|
    US5147125A|1989-08-24|1992-09-15|Viratec Thin Films, Inc.|Multilayer anti-reflection coating using zinc oxide to provide ultraviolet blocking|
    US5688608A|1994-02-10|1997-11-18|Industrial Technology Research Institute|High refractive-index IR transparent window with hard, durable and antireflective coating|
    US5725957A|1994-07-29|1998-03-10|Donnelly Corporation|Transparent substrate with diffuser surface|
    US6001486A|1994-07-29|1999-12-14|Donnelly Corporation|Transparent substrate with diffuser surface|
    US5646780A|1994-08-24|1997-07-08|Honeywell Inc.|Overcoat method and apparatus for ZRO2 mirror stacks|
    US5939189A|1995-05-09|1999-08-17|Flex Products, Inc.|Flexible plastic substrate with anti-reflection coating having low reflective color and method|
    US5812405A|1995-05-23|1998-09-22|Viratec Thin Films, Inc.|Three variable optimization system for thin film coating design|
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    US7507438B2|2004-09-03|2009-03-24|Donnelly Corporation|Display substrate with diffuser coating|
    US8354143B2|2005-05-26|2013-01-15|Tpk Touch Solutions Inc.|Capacitive touch screen and method of making same|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP8424278A|JPS5522704A|1978-07-11|1978-07-11|Multilayer antireflecting film|
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